Crystal Structure of [1-{(2-Oxyphenyl)iminomethyl}benzen- 2-oxy-N,O,O′]cyclopropylamine-Nnickel(II) Complex
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1997
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Abstract
The structures of monomeric Ni complexes in the
presence of a tridentate ONO or ONS Schiff-base ligand
and different monodentate ligands (piperidinel, pyrrolidine2 and cyclohexylamine3) were reported previously. In those complexes the Ni ion has either a square or
distorted square-planar coordination. Here, we report
on the structure of a new Ni complex, which has as a
monodentate ligand the cyclopropylamine molecule
(Fig. 1). As can be seen from Fig. 2, the coordination
around the Ni ion in the title complex is also distorted
square planar. The Ni-0 and Ni-N bond lengths
are [1.814(5) -1.866(5)A] and [1.846(6) -1.929(5)A],